標題: Preparation of a Protected 3-Deoxy-D-manno-oct-2-ulosonate Glycal Donor for the Synthesis of beta-KDO-Containing Oligosaccharides
作者: Pradhan, Tapan Kumar
Lin, Chun Cheng
Mong, Kwok-Kong Tony
應用化學系
Department of Applied Chemistry
公開日期: 7-三月-2014
摘要: A practical method for the synthesis of KDO glycal donors was developed. The prepared KDO donors exhibited excellent disastereoselectivity of glycosylation in a CH2Cl2-CH3CN solvent mixture, which was found to be associated with the isopropylidene protection at the C-4 and C-5 hydroxyls. The synthetic use of the KDO donor was demonstrated in the preparation of beta-KDO-containing oligosaccharides.
URI: http://dx.doi.org/10.1021/ol500275j
http://hdl.handle.net/11536/23988
ISSN: 1523-7060
DOI: 10.1021/ol500275j
期刊: ORGANIC LETTERS
Volume: 16
Issue: 5
起始頁: 1474
結束頁: 1477
顯示於類別:期刊論文


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