標題: | Construction of a photoanode with varied TiO2 nanostructures for a Z907-sensitized solar cell with efficiency exceeding 10% |
作者: | Shiu, Jia-Wei Lan, Zih-Jian Chan, Chien-Yi Wu, Hui-Ping Diau, Eric Wei-Guang 應用化學系 應用化學系分子科學碩博班 Department of Applied Chemistry Institute of Molecular science |
公開日期: | 2014 |
摘要: | For Z907-based dye-sensitized solar cells, we constructed photoanodes, layer by layer, containing titania nanostructures of varied types - spherical nanoparticles (NPs), one-dimensional nanorods (NRs), and octahedron-like nanocrystals of varied size (HD1-HD3), in either a bi-layer (BL) or a multi-layer (ML) film configuration. To understand the kinetics of electron transport in these devices, we measured charge extraction, intensity-modulated photocurrent spectra and photovoltage spectra of devices made of either these nanomaterials or hybrid HD-NP composites (HDP). The HD devices featured an excellent characteristic of electron transport and upward-shifted potentials to produce V-OC greater than those of the NP and NR devices, but the latter featured a larger dye loading to give J(SC) greater than that for the former; the devices fabricated with hybrid HDP films showed enhanced J(SC) and balanced V-OC to perform better than their individual counterparts. We constructed the ML devices based on the NP-BL system with additional HDP layers inserted between the two components, NP and SL, to enhance J(SC) so as to attain the best performance, with efficiency of power conversion (PCE) = 10.1%, at a film thickness (L) of 26 mu m. Because of the robust structural feature of the HD films, the devices fabricated with a simple BL film configuration, HD1/SL = 6/3, exhibited the best performance, PCE = 10.2% at L = 29 mu m, which is a promising advance for Z907-based solar cells with a superior and enduring stability of performance for commercialization. |
URI: | http://hdl.handle.net/11536/24587 http://dx.doi.org/10.1039/c4ta00645c |
ISSN: | 2050-7488 |
DOI: | 10.1039/c4ta00645c |
期刊: | JOURNAL OF MATERIALS CHEMISTRY A |
Volume: | 2 |
Issue: | 23 |
起始頁: | 8749 |
結束頁: | 8757 |
顯示於類別: | 期刊論文 |