| Title: | Synthesis and characterization of novel organic/inorganic hybrid polymers containing polyhedral oligosilsesquioxanes |
| Authors: | Xu, HY Gao, XY Guang, SY Chang, FZ 應用化學系 Department of Applied Chemistry |
| Keywords: | hybrid materials;nanocomposites;poly(vinylpyrrolidone);polysilsesquioxane |
| Issue Date: | 1-Jan-2005 |
| Abstract: | Hybrid polymers, poly(vinyl pyrrolidone-co-isobutyl styryl polyhedral oligomeric silsesquioxanes)s (PVP-POSS) were synthesized by one step polymerization and characterized using GPC and DSC. Addition of POSS significantly increases the Tg of polyvinylpyrrolidone at a fair high POSS content and obtained high molecular weight polymers with very narrow molecular distribution. The POSS content in the resulted hybrids can be controlled by varying the POSS feed ratio. |
| URI: | http://hdl.handle.net/11536/25428 |
| ISSN: | 1001-8417 |
| Journal: | CHINESE CHEMICAL LETTERS |
| Volume: | 16 |
| Issue: | 1 |
| Begin Page: | 41 |
| End Page: | 44 |
| Appears in Collections: | Articles |
- Poly(acetoxystyrene-co-isobutylstyryl POSS) nanocomposites: Characterization and molecular interaction / Xu, HY;Kuo, SW;Huang, CF;Chang, FC
- Glass transition temperatures of poly(hydroxystyrene-co-vinylpyrrolidone-co-isobutylstyry1 polyhedral oligosilsesquioxanes) / Xu, HY;Kuo, SW;Lee, JS;Chang, FC
- Characterization of poly(vinyl pyrrolidone-co-isobutylstyryl polyhedral oligomeric silsesquioxane) nanocomposites / Xu, HY;Kuo, SW;Huang, CF;Chang, FC
- Preparations, thermal properties, and T-g increase mechanism of inorganic/organic hybrid polymers based on polyhedral oligomeric silsesquioxanes / Xu, HY;Kuo, SW;Lee, JS;Chang, FC
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