Highly efficient yellow and white organic electroluminescent devices doped with 2,8-di(t-butyl)-5,11-di[4-(t-butyl)phenyl]-6,12-diphenylnaphthacene

Abstract

We describe the applications of a sterically-hindered yellow dopant, 2,8-di(t-butyl)-5,11-di[4-(t-butyl)phenyl]-6,12-diphenylnaphthacene (TBRb) which, when compared to 5,6,11,12-tetraphenylnaphthacene (Rb) in either tris(8-hydroxyquinolinato)aluminum or 1,4-bis[N-(1-naphthyl)-N-'-phenylamino]-4,4(') diamine (NPB) as host emitter, shows a 50%-34% increase in luminance efficiency over that of Rb device without significantly affecting its color. In addition, we have incorporated the TBRb doped yellow NPB emitter into the two-element white organic light-emitting diodes based on p-bis(p-N,N-di-phenyl-aminostyryl)benzene doped 2-methyl-9,10-di(2-naphthyl) anthracene sky-blue emitter which improved the luminance efficiency by 44% over that of Rb to 12.8 cd/A and 4.3 lm/W at 20 mA/cm(2) with CIEx,y=[0.31,0.38]. (C) 2004 American Institute of Physics.