NMR-STUDY OF EPSILON-CAPROLACTAM IN VARIOUS SOLVENTS - GRAPHICAL DETERMINATION OF MONOMER SHIFT, DIMER SHIFT AND DIMERIZATION CONSTANT FROM THE DILUTION SHIFT DATA

doi:10.1039/FT9949000717

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DC 欄位	值	語言
dc.contributor.author	CHEN, JS	en_US
dc.date.accessioned	2014-12-08T15:04:05Z	-
dc.date.available	2014-12-08T15:04:05Z	-
dc.date.issued	1994-03-07	en_US
dc.identifier.issn	0956-5000	en_US
dc.identifier.uri	http://dx.doi.org/10.1039/FT9949000717	en_US
dc.identifier.uri	http://hdl.handle.net/11536/2585	-
dc.description.abstract	A graphical method for the simultaneous determination of the monomer shift, dimer shift and dimerization constant of a self-association system from the dilution NMR shift data is proposed. This method avoids the conventional extrapolation to infinite dilution to obtain the monomer shift. Three self-association systems: epsilon-caprolactam in [H-2(1)]chloroform, [H-2(3)]acetone and [H-2(3)]acetonitrile were studied at various temperatures. The enthalpy and entropy of dimerization were also determined from van't Hoff plots.	en_US
dc.language.iso	en_US	en_US
dc.title	NMR-STUDY OF EPSILON-CAPROLACTAM IN VARIOUS SOLVENTS - GRAPHICAL DETERMINATION OF MONOMER SHIFT, DIMER SHIFT AND DIMERIZATION CONSTANT FROM THE DILUTION SHIFT DATA	en_US
dc.type	Article	en_US
dc.identifier.doi	10.1039/FT9949000717	en_US
dc.identifier.journal	JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS	en_US
dc.citation.volume	90	en_US
dc.citation.issue	5	en_US
dc.citation.spage	717	en_US
dc.citation.epage	720	en_US
dc.contributor.department	交大名義發表	zh_TW
dc.contributor.department	應用化學系	zh_TW
dc.contributor.department	National Chiao Tung University	en_US
dc.contributor.department	Department of Applied Chemistry	en_US
dc.identifier.wosnumber	WOS:A1994NB14000006	-
dc.citation.woscount	21	-
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