完整後設資料紀錄
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dc.contributor.authorHuang, Chien-Haoen_US
dc.contributor.authorKuo, Te-Wenen_US
dc.contributor.authorChen, Teng-Mingen_US
dc.date.accessioned2014-12-08T15:37:39Z-
dc.date.available2014-12-08T15:37:39Z-
dc.date.issued2011-01-03en_US
dc.identifier.issn1094-4087en_US
dc.identifier.urihttp://dx.doi.org/10.1364/OE.19.0000A1en_US
dc.identifier.urihttp://hdl.handle.net/11536/25899-
dc.description.abstractA class of thermal stable of green-emitting phosphors Ba(3)Y(PO(4))(3):Ce(3+),Tb(3+) (BYP:Ce(3+),Tb(3+)) and red-emitting phosphors Ca(3)Y(AlO)(3)(BO(3))(4):Eu(3+) (CYAB:Eu(3+)) for white-light fluorescent lamps were synthesized by high temperature solid-state reaction. We observed a decay of only 3% at 150 degrees C for BYP:0.25Ce(3+),0.25Tb(3+) (3% for LaPO(4):Ce(3+),Tb(3+)), and a decay of 4% for CYAB:0.5Eu(3+) (7% for Y(2)O(3):Eu(3+), 24% for Y(2)O(2)S:Eu(3+)). The emission intensity of composition-optimized Ba(3)(Y(0.5)Ce(0.25)Tb(0.25))(PO(4))(3) is 70% of that of commercial LaPO(4):Ce(3+),Tb(3+) phosphors, and the CIE chromaticity coordinates are found to be (0.323, 0.534). The emission intensity of Ca(3)(Y(0.5)Eu(0.5))(AlO)(3)(BO(3))(4) is 70% and 83% of those of Y(2)O(3):Eu(3+) and Y(2)O(2)S:Eu(3+) phosphors, respectively, and the CIE chromaticity coordinates are redder (0.652, 0.342) than those of Y(2)O(3):Eu(3+) (0.645, 0.347) and Y(2)O(2)S:Eu(3+) (0.647, 0.343). A white-light fluorescent lamp is fabricated using composition-optimized Ba(3)(Y(0.5)Ce(0.25)Tb(0.25))(PO(4))(3) and Ca(3)(Y(0.5)Eu(0.5))(AlO)(3)(BO(3))(4) phosphors and matching blue-emitting phosphors. The results indicate that the quality of the brightness and color reproduction is suitable for application in shortwave UV fluorescent lamps. The white-light fluorescent lamp displays CIE chromaticity coordinates of x = 0.33, y = 0.35, a warm white light with a correlated color temperature of 5646 K, and a color-rendering index of Ra = 70. (C) 2010 Optical Society of Americaen_US
dc.language.isoen_USen_US
dc.titleThermally stable green Ba(3)Y(PO(4))(3):Ce(3+),Tb(3+) and red Ca(3)Y(AlO)(3)(BO(3))(4):Eu(3+) phosphors for white-light fluorescent lampsen_US
dc.typeArticleen_US
dc.identifier.doi10.1364/OE.19.0000A1en_US
dc.identifier.journalOPTICS EXPRESSen_US
dc.citation.volume19en_US
dc.citation.issue1en_US
dc.citation.spageA1en_US
dc.citation.epageA6en_US
dc.contributor.department應用化學系zh_TW
dc.contributor.departmentDepartment of Applied Chemistryen_US
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