Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Ye, Yun Sheng | en_US |
dc.contributor.author | Cheng, Ming Yao | en_US |
dc.contributor.author | Tseng, Ji Yong | en_US |
dc.contributor.author | Liang, Gao-Wei | en_US |
dc.contributor.author | Rick, John | en_US |
dc.contributor.author | Huang, Yao Jheng | en_US |
dc.contributor.author | Chang, Feng Chih | en_US |
dc.contributor.author | Hwang, Bing Joe | en_US |
dc.date.accessioned | 2014-12-08T15:37:59Z | - |
dc.date.available | 2014-12-08T15:37:59Z | - |
dc.date.issued | 2011 | en_US |
dc.identifier.issn | 0959-9428 | en_US |
dc.identifier.uri | http://hdl.handle.net/11536/26080 | - |
dc.identifier.uri | http://dx.doi.org/10.1039/c0jm02878a | en_US |
dc.description.abstract | New proton conducting membranes, exhibiting a high proton conductivity (10(-2) S cm(-1), without humidification at 160 degrees C), based on the ionic liquid (IL) 1-butyl-3-methylimidazolium tetrafluoroborate (BMIm-BF(4)) were investigated. The incorporation of a similar initial IL loading was found to reduce the proton conductivity loss of a sulfonated polydiacetylene based membrane, i.e. SPDA70-IL70 by 19.2% and IL-based Nafion by 64.6%; additionally, the SPDA70-IL70 was able to maintain a proton conductivity of more than 10(-3) S cm(-1) after centrifugation. The introduction of both a cross-linked structure and a high degree of sulfonation into the polymer matrix, resulted in significant improvements to the membranes' thermal properties, the dispersion of ionic domains, and the retention of IL-together with a reduction of proton conductivity loss. The membranes, which have a high degree of sulfonation with thermally cross-linkable diacetylene in the polymer's main chain, avoid the drawback of poor miscibility commonly associated with sulfonated polymers and cross-linking agents. When the composite membrane was used in a H(2)/O(2) fuel cell without humidification at 100 degrees C, a power density > 250 mA cm(-2) was achieved together with a maximum current denisty of 122 mW cm(-2). | en_US |
dc.language.iso | en_US | en_US |
dc.title | New proton conducting membranes with high retention of protic ionic liquids | en_US |
dc.type | Article | en_US |
dc.identifier.doi | 10.1039/c0jm02878a | en_US |
dc.identifier.journal | JOURNAL OF MATERIALS CHEMISTRY | en_US |
dc.citation.volume | 21 | en_US |
dc.citation.issue | 8 | en_US |
dc.citation.spage | 2723 | en_US |
dc.citation.epage | 2732 | en_US |
dc.contributor.department | 應用化學系 | zh_TW |
dc.contributor.department | Department of Applied Chemistry | en_US |
dc.identifier.wosnumber | WOS:000287092000046 | - |
dc.citation.woscount | 10 | - |
Appears in Collections: | Articles |
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