標題: | Reactive resonance in a polyatomic reaction |
作者: | Shiu, W Lin, JJ Liu, KP 應用化學系 Department of Applied Chemistry |
公開日期: | 12-三月-2004 |
摘要: | In the course of an extensive investigation aimed at understanding the detailed mechanisms of a prototypical polyatomic reaction, several remarkable observations were uncovered. To interpret these findings, we surmise the existence of a reactive resonance in this polyatomic reaction. The reaction of concern is F+CH4-->HF+CH3, and the abnormal attributes were revealed only near the reaction threshold. The discovery of reactive resonance in a polyatomic reaction is more than just an extension from a typical atom+diatom reaction. As shown here, it holds great promise to disentangle the elusive intramolecular vibrational dynamics of transient collision complex in the critical transition-state region. |
URI: | http://dx.doi.org/10.1103/PhysRevLett.92.103201 http://hdl.handle.net/11536/26948 |
ISSN: | 0031-9007 |
DOI: | 10.1103/PhysRevLett.92.103201 |
期刊: | PHYSICAL REVIEW LETTERS |
Volume: | 92 |
Issue: | 10 |
起始頁: | 0 |
結束頁: | 0 |
顯示於類別: | 期刊論文 |