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dc.contributor.authorLeu, CMen_US
dc.contributor.authorChang, YTen_US
dc.contributor.authorWei, KHen_US
dc.date.accessioned2014-12-08T15:40:00Z-
dc.date.available2014-12-08T15:40:00Z-
dc.date.issued2003-12-02en_US
dc.identifier.issn0024-9297en_US
dc.identifier.urihttp://dx.doi.org/10.1021/ma034743ren_US
dc.identifier.urihttp://hdl.handle.net/11536/27326-
dc.description.abstractPolyimide-tethered polyhedral oligomeric silsesquioxane, (R7R'Si8O12) (POSS), nanocomposites with well-defined architectures are prepared by the copolymerization reaction of a new type of diamine monomer: POSS-diamine, 4,4'-oxydianiline (ODA), and pyromellitic dianhydride (PMDA). This type of polyimide-side-chain-tethered POSS nanocomposite presents self-assembly characteristics when the amount of POSS exceeds 10 mol %, as evidenced by transmission electron microscopy studies. Furthermore, POSS/polyimide nanocomposites have both lower and tunable dielectric constants, with the lowest value of 2.3, and controllable mechanical properties, as compared to that of pure polyimide.en_US
dc.language.isoen_USen_US
dc.titleSynthesis and dielectric properties of polyimide-tethered polyhedral oligomeric silsesquioxane (POSS) nanocomposites via POSS-diamineen_US
dc.typeArticleen_US
dc.identifier.doi10.1021/ma034743ren_US
dc.identifier.journalMACROMOLECULESen_US
dc.citation.volume36en_US
dc.citation.issue24en_US
dc.citation.spage9122en_US
dc.citation.epage9127en_US
dc.contributor.department材料科學與工程學系zh_TW
dc.contributor.departmentDepartment of Materials Science and Engineeringen_US
dc.identifier.wosnumberWOS:000186857700028-
dc.citation.woscount145-
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