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dc.contributor.authorChen, HWen_US
dc.contributor.authorChiu, CYen_US
dc.contributor.authorWu, HDen_US
dc.contributor.authorShen, IWen_US
dc.contributor.authorChang, FCen_US
dc.date.accessioned2014-12-08T15:42:06Z-
dc.date.available2014-12-08T15:42:06Z-
dc.date.issued2002-08-01en_US
dc.identifier.issn0032-3861en_US
dc.identifier.urihttp://dx.doi.org/10.1016/S0032-3861(02)00326-9en_US
dc.identifier.urihttp://hdl.handle.net/11536/28604-
dc.description.abstractThis work has demonstrated that the addition of specific amount of poly(oxypropylene) diamine (d2000) and mineral clay in the PEO-based electrolyte system can form the high conductivity film at room temperature. Specific interactions among silicate layer, d2000, ether oxygen, and lithium cation have been investigated using differential scanning calorimetry (DSC), alternating current impedance (AC impedance) and Fourier-transform infrared (FT-IR). The DSC characterization confirms that the addition of 25 w1% d2000 is able to produce low T-g and fully amorphous (PEO)(8)LiClO4/d2000 electrolyte system which produce the good environment for ionic transfer. Additionally, the incorporation of the mineral clay into the (PEO)(8)LiClO4/d2000 electrolyte system can sustain the polymeric mechanical property by its huge surface area and enhance the conductivity due to the specific interaction between silicate layers and lithium cation. FT-IR spectra confirm that the incorporation of the clay is able to dissolve the lithium salts more effectively and resulting to the higher fraction of free anions due to the strong interaction between negative charges of the silicate layers and lithium cations of the lithium salt. (C) 2002 Elsevier Science Ltd. All rights reserved.en_US
dc.language.isoen_USen_US
dc.subjectpolymeric electrolytesen_US
dc.subjectmineral clayen_US
dc.subjectpoly(oxypropylene) diamineen_US
dc.titleSolid-state electrolyte nanocomposites based on poly(ethylene oxide), poly(oxypropylene) diamine, mineral clay and lithium perchlorateen_US
dc.typeArticleen_US
dc.identifier.doi10.1016/S0032-3861(02)00326-9en_US
dc.identifier.journalPOLYMERen_US
dc.citation.volume43en_US
dc.citation.issue18en_US
dc.citation.spage5011en_US
dc.citation.epage5016en_US
dc.contributor.department應用化學系zh_TW
dc.contributor.departmentDepartment of Applied Chemistryen_US
dc.identifier.wosnumberWOS:000177203900020-
dc.citation.woscount54-
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