標題: Intrachain carrier transport in conjugated polymer with structural and chemical defects
作者: Chen, YS
Meng, HF
物理研究所
Institute of Physics
公開日期: 15-七月-2002
摘要: By calculating the phase shifts of the wave functions for the extended scattering states within tight-binding model for a poly (p-phenylene vinylene) chain with one conjugation defect, we obtain the exact transmission probability through the defect as a function of the carrier incident energy for the entire eight pi bands. Cis-defect, sp(3) saturation, and oxidation are considered. The transmission increases rapidly from zero with the carrier kinetic energy, implying the conjugation breaks do not severely limit the intrachain charge transport under high electric field. Assuming an average conjugation length of 100 Angstrom separated by cis-defects, the drift velocity is predicted to be as high as 10(3) m/s for field at 10(7) V/m, and over 10(5) m/s at 10(8) V/m.
URI: http://dx.doi.org/10.1103/PhysRevB.66.035202
http://hdl.handle.net/11536/28661
ISSN: 2469-9950
DOI: 10.1103/PhysRevB.66.035202
期刊: PHYSICAL REVIEW B
Volume: 66
Issue: 3
起始頁: 0
結束頁: 0
顯示於類別:期刊論文


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