Synthesis of tacamonine

標題:	Synthesis of tacamonine
作者:	Ho, TL Gorobets, E 應用化學系 Department of Applied Chemistry
關鍵字:	tacamonine;mannich reaction;Beckmann fragmentation
公開日期:	10-Jun-2002
摘要:	Tacamonine has been synthesized in 3.2% overall yield from cyclohexanone-4-carboxylic acid ethyleneacetal. The tetrahydro-beta-carboline intermediate was submitted to a Mannich reaction to provide a bridged ring system embodying latent branches of the quinolizidine portion. The final stages included fragmentation and Grignard reaction. (C) 2002 Published by Elsevier Science Ltd.
URI:	http://dx.doi.org/10.1016/S0040-4020(02)00395-2 http://hdl.handle.net/11536/28723
ISSN:	0040-4020
DOI:	10.1016/S0040-4020(02)00395-2
期刊:	TETRAHEDRON
Volume:	58
Issue:	24
起始頁:	4969
結束頁:	4973
Appears in Collections:	Articles

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