Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kuo, SW | en_US |
dc.contributor.author | Chang, FC | en_US |
dc.date.accessioned | 2014-12-08T15:42:38Z | - |
dc.date.available | 2014-12-08T15:42:38Z | - |
dc.date.issued | 2002-03-28 | en_US |
dc.identifier.issn | 1022-1352 | en_US |
dc.identifier.uri | http://hdl.handle.net/11536/28925 | - |
dc.identifier.uri | http://dx.doi.org/10.1002/1521-3935(20020401)203:5/6<868 | en_US |
dc.description.abstract | The miscibility behavior and specific interaction of phenolic resin with poly(acetoxystyrene) (PAS) blends were examined using differential scanning calorimetry (DSC), fourier-transform infrared (FT-IR) spectroscopy and solid-state NMR. This phenolic/PAS blend is fully miscible, as indicated by a single glass-transition temperature, due to the formation of inter-hydrogen bonding between the hydroxyl group of the phenolic resin and the carbonyl group of PAS. The DSC study indicates that this phase-separation exothermic peak area is closely related to the interaction between the components. Furthermore, C-13 solid-state NMR and FT-IR spectroscopies were used to study the extent of specific interaction with various compositions and degrees of inter- and intramolecular hydrogen bonding, Moreover, the inter-association equilibrium constant and the related enthalpy of this phenolic/PAS blend were determined and used to predict the free energy and fraction of the hydrogen bonding according to the Painter-Coleman association model. | en_US |
dc.language.iso | en_US | en_US |
dc.subject | blends | en_US |
dc.subject | FTIR | en_US |
dc.subject | miscibility | en_US |
dc.subject | polystyrene | en_US |
dc.subject | resins | en_US |
dc.title | Miscibility behavior and specific interaction of phenolic resin with poly(acetoxystyrene) blends | en_US |
dc.type | Article | en_US |
dc.identifier.doi | 10.1002/1521-3935(20020401)203:5/6<868 | en_US |
dc.identifier.journal | MACROMOLECULAR CHEMISTRY AND PHYSICS | en_US |
dc.citation.volume | 203 | en_US |
dc.citation.issue | 5-6 | en_US |
dc.citation.spage | 868 | en_US |
dc.citation.epage | 878 | en_US |
dc.contributor.department | 應用化學系 | zh_TW |
dc.contributor.department | Department of Applied Chemistry | en_US |
dc.identifier.wosnumber | WOS:000175046900010 | - |
dc.citation.woscount | 27 | - |
Appears in Collections: | Articles |
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