標題: Poly(acetoxystyrene-co-isobutylstyryl POSS) nanocomposites: Characterization and molecular interaction
作者: Xu, HY
Kuo, SW
Huang, CF
Chang, FC
應用化學系
Department of Applied Chemistry
關鍵字: glass transition temperature;hybrid materials;nanocomposites;poly(acetoxystyrene);polysiloxanes;polysilsesquioxane
公開日期: 2002
摘要: The poly (acetoxy styrene-co-isobutyl styryl polyhedral oligomeric silsesquioxanes)s (PAS-POSS) were synthesized by free radical polymerization and characterized by FTIR, high resolution NMR, FTIR, GPC, and DSC. The results show that the POSS content can be controlled by varying the POSS feed ratios. The interactions between organic components and inorganic POSS core, and the effects of inorganic POSS core on the properties of the resulting hybrids were investigated by high resolution solid state C-13 NMR, Si-29 NMR and FTIR spectra. The results provide detailed understandings of the effects of POSS moiety on properties of hybrid polymers.
URI: http://hdl.handle.net/11536/29075
http://dx.doi.org/10.1023/A:1021303818406
ISSN: 1022-9760
DOI: 10.1023/A:1021303818406
期刊: JOURNAL OF POLYMER RESEARCH-TAIWAN
Volume: 9
Issue: 4
起始頁: 239
結束頁: 244
顯示於類別:期刊論文


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