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dc.contributor.authorChou, SSen_US
dc.contributor.authorHuang, CPen_US
dc.contributor.authorHuang, YHen_US
dc.date.accessioned2014-12-08T15:44:03Z-
dc.date.available2014-12-08T15:44:03Z-
dc.date.issued2001-03-15en_US
dc.identifier.issn0013-936Xen_US
dc.identifier.urihttp://dx.doi.org/10.1021/es001129ben_US
dc.identifier.urihttp://hdl.handle.net/11536/29768-
dc.description.abstractOxidation of benzoic,acid (BA) by H2O2 was performed with a never supported gamma -FeOOH catalyst in a circulating fluidized-bed reactor (CFBR).; This study focused mainly on determining the proportions of homogeneous catalysis and heterogeneous catalysis in this CFBR. Also studied herein was how pH, H2O2 concentration, and BA concentration affect the oxidation of BA. Experimental results indicate that the decomposition rate of H2O2 was proportional to its concentration and that the oxidation rate of BA depended on both H2O2 and BA concentrations. The change in the rate constant of heterogeneous catalysis by pH was described in terms of ionization fractions of surface hydroxyl group. From the mathematical deduction, we-can infer that the reaction rate associated with equivalent toF(III)OH(2)(+) is markedly higher than that with equivalent toF(III)OH. Conclusively, although heterogeneous catalysis contributes primarily to the oxidation of BA at pH 4.4-7.0, the homogeneous catalysis is of increasing importance below pH 4.4 because of the reductive dissolution of gamma -FeOOH.en_US
dc.language.isoen_USen_US
dc.titleHeterogeneous and homogeneous catalytic oxidation by supported gamma-FeOOH in a fluidized bed reactor: Kinetic approachen_US
dc.typeArticleen_US
dc.identifier.doi10.1021/es001129ben_US
dc.identifier.journalENVIRONMENTAL SCIENCE & TECHNOLOGYen_US
dc.citation.volume35en_US
dc.citation.issue6en_US
dc.citation.spage1247en_US
dc.citation.epage1251en_US
dc.contributor.department環境工程研究所zh_TW
dc.contributor.departmentInstitute of Environmental Engineeringen_US
dc.identifier.wosnumberWOS:000167529700036-
dc.citation.woscount68-
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