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dc.contributor.authorLi, YSen_US
dc.contributor.authorChang, FCen_US
dc.date.accessioned2014-12-08T15:44:06Z-
dc.date.available2014-12-08T15:44:06Z-
dc.date.issued2001-03-01en_US
dc.identifier.issn1022-9760en_US
dc.identifier.urihttp://hdl.handle.net/11536/29783-
dc.description.abstractThe cationic reaction of an epoxy/BF3-MEA system occurs between the oxirane group and the oxonium group, The addition of polycarbonate to the system does not cause a transesterification reaction between the carbonate group and the oxonium group, thus the molecular weight of the PC is unchanged during the reaction. PC crystallization is observed in the cured system because the epoxy monomer accelerates the PC crystallization. The eposy/BF3-MEA and epoxy/PC/BF3-MEA systems all follow the first order reaction. The PC modified systems show lower activation energy, a lower pre-exponential factor and a higher reaction rate constant.en_US
dc.language.isoen_USen_US
dc.subjectepoxyen_US
dc.subjectpolycarbonateen_US
dc.subjectboron trifluoride complexen_US
dc.subjectkinetic parameteren_US
dc.titleThe reactivity of epoxy/polycarbonate/BF3-MEA systemen_US
dc.typeArticleen_US
dc.identifier.journalJOURNAL OF POLYMER RESEARCH-TAIWANen_US
dc.citation.volume8en_US
dc.citation.issue1en_US
dc.citation.spage1en_US
dc.citation.epage7en_US
dc.contributor.department應用化學系zh_TW
dc.contributor.departmentDepartment of Applied Chemistryen_US
dc.identifier.wosnumberWOS:000168689800001-
dc.citation.woscount4-
Appears in Collections:Articles


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