完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.author | Luo, WC | en_US |
dc.contributor.author | Lay, JL | en_US |
dc.contributor.author | Chen, JS | en_US |
dc.date.accessioned | 2014-12-08T15:44:20Z | - |
dc.date.available | 2014-12-08T15:44:20Z | - |
dc.date.issued | 2001 | en_US |
dc.identifier.issn | 0942-9352 | en_US |
dc.identifier.uri | http://hdl.handle.net/11536/29949 | - |
dc.identifier.uri | http://dx.doi.org/10.1524/zpch.2001.215.1.001 | en_US |
dc.description.abstract | This study investigates the association of 2-isopropylphenol through hydrogen bonding in carbon tetrachloride, [H-2(6)]acetone, [H-2(3)]acetonitrile and [H-2(6)]dimethyl sulphoxide by using high resolution nuclear magnetic resonance spectroscopy. Chemical shifts of the hydroxyl proton were measured over a wide range of temperature and concentration. The chemical shift data were treated by a graphical method to determine the monomer shift, dimer shift and dimerization constant. The enthalpy and entropy of dimerization were determined via a van't Hoff plot from the temperature variation of the dimerization constant. | en_US |
dc.language.iso | en_US | en_US |
dc.subject | graphical determination | en_US |
dc.subject | monomer shift | en_US |
dc.subject | dimer shift | en_US |
dc.subject | dimerization constant | en_US |
dc.title | NMR study of hydrogen bonding association of 2-isopropylphenol in carbon tetrachloride, acetone, dimethyl sulphoxide and acetonitrile | en_US |
dc.type | Article | en_US |
dc.identifier.doi | 10.1524/zpch.2001.215.1.001 | en_US |
dc.identifier.journal | ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS | en_US |
dc.citation.volume | 215 | en_US |
dc.citation.spage | 1 | en_US |
dc.citation.epage | 12 | en_US |
dc.contributor.department | 應用化學系 | zh_TW |
dc.contributor.department | Department of Applied Chemistry | en_US |
dc.identifier.wosnumber | WOS:000166646400001 | - |
dc.citation.woscount | 3 | - |
顯示於類別: | 期刊論文 |