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dc.contributor.authorLuo, WCen_US
dc.contributor.authorChen, JSen_US
dc.date.accessioned2014-12-08T15:44:20Z-
dc.date.available2014-12-08T15:44:20Z-
dc.date.issued2001en_US
dc.identifier.issn0942-9352en_US
dc.identifier.urihttp://hdl.handle.net/11536/29950-
dc.identifier.urihttp://dx.doi.org/10.1524/zpch.2001.215.4.447en_US
dc.description.abstractThe self-association of acetanilide through hydrogen bonding between N-H and O=C in the solvents [H-2(1)]chloroform, [H-2(6)]acetone, [H-2(3)]acetonitrile and [H-2(6)]dimethyl sulphoxide is investigated by high resolution nuclear magnetic resonance spectroscopy. Dilution shift data for the protons of the N-H group were measured over a wide range of temperature and concentration. The monomer shift, dimer shift and dimerization constant were determined by a graphical method operating on the dilution chemical shift data. The enthalpy and entropy of dimerization were also obtained from the van't Hoff plot.en_US
dc.language.isoen_USen_US
dc.subjectdimerizationen_US
dc.subjectgraphical methoden_US
dc.subjectmonomer shiften_US
dc.subjectdimer shiften_US
dc.titleNMR study of self-association of acetanilide in chloroform, acetone, acetonitrile and dimethyl sulphoxideen_US
dc.typeArticleen_US
dc.identifier.doi10.1524/zpch.2001.215.4.447en_US
dc.identifier.journalZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICSen_US
dc.citation.volume215en_US
dc.citation.spage447en_US
dc.citation.epage459en_US
dc.contributor.department應用化學系zh_TW
dc.contributor.departmentDepartment of Applied Chemistryen_US
dc.identifier.wosnumberWOS:000168282100002-
dc.citation.woscount4-
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