標題: Intramolecular Diels-Alder reaction of furans with allenyl ethers followed by phenylthio and trialkylsilyl groups rearrangement
作者: Chuang, CT
Yen, CH
Wu, HJ
應用化學系
Department of Applied Chemistry
關鍵字: intramolecular Diels-Alder reaction;furans;allenyl ethers;phenylthio group rearrangement;trialkylsilyl group rearrangement
公開日期: 1-十二月-1998
摘要: a new reaction involving an intramolecular Diels-Alder reaction of a furan diene with an allenyl ether dienophile followed by phenylthio group rearrangement was discovered. Treatment of the propargyl ethers 2a-c with t-BuOK in t-BuOH at 85 degrees C gave the phenylthio group rearrangement products 5a-c and 6a-c. A reaction involving an intramolecular Diels-Alder reaction of a furan diene with an allenyl ether dienophile followed by trialkylsilyl group rearrangement is also demonstrated.
URI: http://hdl.handle.net/11536/31705
ISSN: 0009-4536
期刊: JOURNAL OF THE CHINESE CHEMICAL SOCIETY
Volume: 45
Issue: 6
起始頁: 789
結束頁: 797
顯示於類別:期刊論文