Title: | Synthesis of dioxa-cages as a new probe for the stereochemistry of the bisadducts of p-quinone with cyclopentadiene and cyclohexadiene |
Authors: | Yen, CH Tsai, SH Wu, HJ 應用化學系 Department of Applied Chemistry |
Keywords: | synthesis of dioxa-cages;bisadducts of p-quinone with cyclopentadiene and cyclohexadiene |
Issue Date: | 1-Dec-1998 |
Abstract: | The synthesis of dioxa-cages via iodine-induced cyclization reaction can be used as a new method for the determination of the stereochemistry of the bisadducts of p-quinone with cyclopentadiene and cyclohexadiene. The bisadducts 2 and 8 were converted into the dioxa-cages 13a and 13b via a three-step sequence, respectively. The stereochemistry of 13a and 13b was determined on the basis of NOE experiments. |
URI: | http://hdl.handle.net/11536/31706 |
ISSN: | 0009-4536 |
Journal: | JOURNAL OF THE CHINESE CHEMICAL SOCIETY |
Volume: | 45 |
Issue: | 6 |
Begin Page: | 799 |
End Page: | 804 |
Appears in Collections: | Articles |