SYNTHESIS OF HIGH-TEMPERATURE MESOMORPHIC POLYSILOXANES AND THEIR USE AS STATIONARY PHASES FOR HIGH-RESOLUTION GAS-CHROMATOGRAPHY

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DC 欄位	值	語言
dc.contributor.author	LIN, JL	en_US
dc.contributor.author	HSU, CS	en_US
dc.date.accessioned	2014-12-08T15:04:42Z	-
dc.date.available	2014-12-08T15:04:42Z	-
dc.date.issued	1993	en_US
dc.identifier.issn	0032-3896	en_US
dc.identifier.uri	http://hdl.handle.net/11536/3197	-
dc.description.abstract	Two new liquid crystalline polysiloxanes with very wide mesomorphic temperature range have been prepared. One containing 4-[(S)-2-methyl-1-butoxy]phenyl 4-hexanyloxy-biphenyl-4'-carboxylate side groups displays enantiotropic smectic A, chiral smectic C and smectic B phases. The other containing (S)-2-methyl-1-butyl 6-(4-undecanyloxybiphenyl-4'-carbonyloxy)-2-naphthalenecarboxylate side groups exhibits only an enantiotropic cholesteric phase. Both mesomorphic polysiloxanes were used as stationary phases in gas chromatography capillary columns. They show very unique separating properties for various isomeric halogenated naphthalene compounds, methylanthracene compounds, fatty acid methyl esters and polycyclic aromatic compounds.	en_US
dc.language.iso	en_US	en_US
dc.subject	LIQUID CRYSTALLINE POLYMERS	en_US
dc.subject	MESOMORPHIC POLYSILOXANES	en_US
dc.subject	GAS CHROMATOGRAPHY	en_US
dc.subject	LIQUID CRYSTAL STATIONARY PHASES	en_US
dc.title	SYNTHESIS OF HIGH-TEMPERATURE MESOMORPHIC POLYSILOXANES AND THEIR USE AS STATIONARY PHASES FOR HIGH-RESOLUTION GAS-CHROMATOGRAPHY	en_US
dc.type	Article	en_US
dc.identifier.journal	POLYMER JOURNAL	en_US
dc.citation.volume	25	en_US
dc.citation.issue	2	en_US
dc.citation.spage	153	en_US
dc.citation.epage	167	en_US
dc.contributor.department	應用化學系	zh_TW
dc.contributor.department	Department of Applied Chemistry	en_US
dc.identifier.wosnumber	WOS:A1993KN22600005	-
dc.citation.woscount	9	-
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