標題: | SYNTHESIS AND CHARACTERIZATION OF CHIRAL SMECTIC SIDE-CHAIN LIQUID-CRYSTALLINE POLYSILOXANES CONTAINING 2,5-DISUBSTITUTED-1,3-DIOXANE BASED MESOGENIC SIDE-GROUPS |
作者: | JUANG, TM LEU, YJ HSU, CS 應用化學系 Department of Applied Chemistry |
關鍵字: | FERROELECTRIC LIQUID CRYSTAL;SIDE-CHAIN LIQUID CRYSTALLINE POLYMER;TRANS-1,3-DIOXANE-BASED MESOGEN;POLYSILOXANE BACKBONE |
公開日期: | 1993 |
摘要: | The synthesis of three liquid crystalline polysiloxanes containing 4-[(S)-2-methyl-1-butoxycarbonyl]phenyl 4-(trans-5-alkanyl-1,3-dioxan-2-yl]benzoates side groups is presented. The phase behavior of both monomeric and polymeric liquid crystals was characterized by optical polarizing microscopy, differential scanning calorimetry and X-ray diffraction measurements. The monomer which contains eleven methylene units in the spacers is the only one to exhibit the enantiotropic smectic A and chiral smectic C phases. The polymer containing six methylene units in the spacers presents an enantiotropic smectic A phase while the polymer containing eleven methylene units in the spacers shows an enantiotropic smectic A and a monotropic smectic B phase. |
URI: | http://hdl.handle.net/11536/3198 http://dx.doi.org/10.1080/10587259308030138 |
ISSN: | 1058-725X |
DOI: | 10.1080/10587259308030138 |
期刊: | MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS |
Volume: | 237 |
起始頁: | 223 |
結束頁: | & |
顯示於類別: | 期刊論文 |