標題: | Preparation and Characterizations of Tantalum Pentoxide (Ta(2)O(5)) Nanoparticles and UV-Curable Ta(2)O(5)-Acrylic Nanocomposites |
作者: | Huang, Heh-Chang Hsieh, Tsung-Eong 材料科學與工程學系 Department of Materials Science and Engineering |
公開日期: | 5-Aug-2010 |
摘要: | Tantalum pentoxide (Ta(2)O(5)) nanoparticles with the sizes in the range of 20-50 nm were prepared via a chemical route in which the oleic acid (OLEA) was adopted as the surfactant for the synthesis process. X-ray diffraction (XRD) revealed the as-synthesized Ta(2)O(5) transforms from amorphous to hexagonal and ortho-rhombic structures at the temperatures of 700 degrees C and 750 degrees C, respectively, illustrating the suppression of recrystallization temperature of Ta(2)O(5) due to the particle size reduction. UV-curable nanocomposites containing the Ta(2)O(5) nanoparticles and acrylic matrix were also prepared. Thermogravimetry analysis (TGA) found an about 10-20 degrees C improvement on the 5% weight-loss thermal decomposition temperatures (T(d)s). Dielectric measurement showed that the dielectric constant of nanocomposite increases with the increase in the filler loading without severe deterioration of dielectric loss. The increment of dielectric constants was ascribed to the addition of high-dielectric inorganic fillers as well as the presence of interfacial polarization at the organic/inorganic interfaces. (C) 2010 Wiley Periodicals, Inc. J Appl Polym Sci 117: 1252-1259, 2010 |
URI: | http://dx.doi.org/10.1002/app.31709 http://hdl.handle.net/11536/32308 |
ISSN: | 0021-8995 |
DOI: | 10.1002/app.31709 |
期刊: | JOURNAL OF APPLIED POLYMER SCIENCE |
Volume: | 117 |
Issue: | 3 |
起始頁: | 1252 |
結束頁: | 1259 |
Appears in Collections: | Articles |