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dc.contributor.authorLII, KHen_US
dc.contributor.authorLI, CHen_US
dc.contributor.authorCHEN, TMen_US
dc.contributor.authorWANG, SLen_US
dc.date.accessioned2014-12-08T15:05:22Z-
dc.date.available2014-12-08T15:05:22Z-
dc.date.issued1991en_US
dc.identifier.issn0044-2968en_US
dc.identifier.urihttp://hdl.handle.net/11536/3909-
dc.identifier.urihttp://dx.doi.org/10.1524/zkri.1991.197.1-2.67en_US
dc.description.abstractA new sodium vanadyl(IV) orthophosphate NaVOPO4 has been synthesized by solid-state and hydrothermal method and characterized by single-crystal X-ray diffraction and magnetic susceptibility. It crystallizes in the monoclinic space group P2(1)/c with a = 6.524(1), b = 8.455(4), c = 7.119(1), beta = 115.29(1)-degrees, Z = 4, R = 0.027, and is structurally similar to the triclinic analog LiVOPO4. The structure can be described as close-packed infinite chains of trans-corner-sharing VO6 octahedra with the holes around each chain filled with Na and P atoms. These infinite chains have alternating short and long V - O bonds and are similar to those found in beta-VOPO4. The Na atom has six close oxygen neighbors at distances of 2.268 to 2.511 angstrom.en_US
dc.language.isoen_USen_US
dc.subjectCRYSTAL STRUCTUREen_US
dc.subjectMAGNETIC SUSCEPTIBILITYen_US
dc.subjectVANADYL PHOSPHATEen_US
dc.titleSYNTHESIS AND STRUCTURAL CHARACTERIZATION OF SODIUM VANADYL(IV) ORTHOPHOSPHATE NAVOPO4en_US
dc.typeArticleen_US
dc.identifier.doi10.1524/zkri.1991.197.1-2.67en_US
dc.identifier.journalZEITSCHRIFT FUR KRISTALLOGRAPHIEen_US
dc.citation.volume197en_US
dc.citation.issue1-2en_US
dc.citation.spage67en_US
dc.citation.epage73en_US
dc.contributor.department應用化學系zh_TW
dc.contributor.departmentDepartment of Applied Chemistryen_US
dc.identifier.wosnumberWOS:A1991GK37000007-
dc.citation.woscount50-
Appears in Collections:Articles