利用間質隔離法研究CS2與Cl2在para-H2間質中的雷射光解反應

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DC Field	Value	Language
dc.contributor.author	黃瓊緯	en_US
dc.contributor.author	Huang, Chiung-Wei	en_US
dc.contributor.author	李遠鵬	en_US
dc.contributor.author	Lee, Yuan-Pern	en_US
dc.date.accessioned	2014-12-12T01:34:46Z	-
dc.date.available	2014-12-12T01:34:46Z	-
dc.date.issued	2008	en_US
dc.identifier.uri	http://140.113.39.130/cdrfb3/record/nctu/#GT079658508	en_US
dc.identifier.uri	http://hdl.handle.net/11536/43567	-
dc.description.abstract	本論文利用低溫間質隔離技術搭配霍氏轉換紅外光譜儀（FTIR）研究CS2與Cl2在para-H2（p-H2）間質中的雷射光解反應。利用p-H2間質的無晶格效應，以340 nm光解Cl2產生的Cl原子和CS2形成ClSCS，接著觀察到此產物在355 nm光解光源時如預期地減少，並以34S和13C同位素取代實驗及理論計算的配合鑑定此分子的ν1振動模吸收頻率。由355 nm造成的光解產物可再經由不同反應途徑形成其他產物，如本實驗也觀察到ClCS和trans-Cl2CS2。另外，cis-Cl2CS2只有在以308 nm雷射光解樣品間質時生成。	zh_TW
dc.language.iso	zh_TW	en_US
dc.subject	氯氣	zh_TW
dc.subject	二硫化碳	zh_TW
dc.subject	間質隔離	zh_TW
dc.subject	紅外吸收光譜	zh_TW
dc.subject	chlorine	en_US
dc.subject	carbon disulfide	en_US
dc.subject	matrix isolation	en_US
dc.subject	infrared spectra	en_US
dc.title	利用間質隔離法研究CS2與Cl2在para-H2間質中的雷射光解反應	zh_TW
dc.title	Reactions between CS2 and Cl2 in para-H2 after Photoirradiation upon Matrix Isolation Method	en_US
dc.type	Thesis	en_US
dc.contributor.department	應用化學系碩博士班	zh_TW
Appears in Collections:	Thesis

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