Direct Observation of the Molecular Structural Changes during the Claisen Rearrangement Including the Transition State

doi:10.1246/cl.2010.374

完整後設資料紀錄

DC 欄位	值	語言
dc.contributor.author	Iwakura, Izumi	en_US
dc.contributor.author	Yabushita, Atushi	en_US
dc.contributor.author	Kobayashi, Takayoshi	en_US
dc.date.accessioned	2014-12-08T15:07:03Z	-
dc.date.available	2014-12-08T15:07:03Z	-
dc.date.issued	2010-04-05	en_US
dc.identifier.issn	0366-7022	en_US
dc.identifier.uri	http://dx.doi.org/10.1246/cl.2010.374	en_US
dc.identifier.uri	http://hdl.handle.net/11536/5526	-
dc.description.abstract	The detailed processes in the Claisen rearrangement were observed. The process was vibrationally excited in the electronic ground state by a stimulated Raman process using a 5-fs pulse. The Claisen rearrangement was found to follow a three-step pathway. At first, the C(4)-O bond is weakened to generate a bis-allyl-like intermediate. Next, the formation of a weak C(1)-C(6) bond results in the generation of an aromatic-like intermediate. Finally, C(4)-O breaking and C(1)-C(6) formation occur simultaneously to generate the product.	en_US
dc.language.iso	en_US	en_US
dc.title	Direct Observation of the Molecular Structural Changes during the Claisen Rearrangement Including the Transition State	en_US
dc.type	Article	en_US
dc.identifier.doi	10.1246/cl.2010.374	en_US
dc.identifier.journal	CHEMISTRY LETTERS	en_US
dc.citation.volume	39	en_US
dc.citation.issue	4	en_US
dc.citation.spage	374	en_US
dc.citation.epage	375	en_US
dc.contributor.department	電子物理學系	zh_TW
dc.contributor.department	Department of Electrophysics	en_US
dc.identifier.wosnumber	WOS:000277209300027	-
dc.citation.woscount	17	-
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