標題: | Theoretical studies of ZEKE spectroscopy and dynamics of high Rydberg states |
作者: | Wang, Yi-Hsieh Teranishi, Y. Mineo, H. Chao, S. D. Selzle, H. L. Neusser, H. J. Schlag, E. W. Lin, S. H. 應用化學系分子科學碩博班 Institute of Molecular science |
公開日期: | 12-Feb-2010 |
摘要: | A main purpose of this Letter is to show how to employ the inverse Born-Oppenheimer approximation as a basis set to study zero kinetic energy (ZEKE) spectroscopy and the autoionization dynamics of the ZEKE states. The calculations of channel couplings, quantum defects, intensity borrowing, vibrational and rotational autotionizations will be demonstrated by using a homonuclear diatomic molecule as an example. (C) 2010 Elsevier B. V. All rights reserved. |
URI: | http://dx.doi.org/10.1016/j.cplett.2009.12.092 http://hdl.handle.net/11536/5842 |
ISSN: | 0009-2614 |
DOI: | 10.1016/j.cplett.2009.12.092 |
期刊: | CHEMICAL PHYSICS LETTERS |
Volume: | 486 |
Issue: | 4-6 |
起始頁: | 104 |
結束頁: | 109 |
Appears in Collections: | Articles |
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