標題: | Resonance Effect on Self- and Inter-Association Hydrogen Bonding Interaction of Polymer Blend |
作者: | Lin, Chien-Ting Kuo, Shiao-Wei Lo, Jen-Chih Chang, Feng-Chih 應用化學系 Department of Applied Chemistry |
公開日期: | 4-二月-2010 |
摘要: | A comparative Study of three poly(methacrylamides) containing different N-substitutions was carried Out in order to obtain a better understanding of the resonance effects on the inter-association and self-association hydrogen bonding interactions in polymer blends. DSC and solid-state NMR analyses are employed to Study the relative miscibility of these three binary blends, indicating that the PNPAA/P4VP blend has a better miscibility than the PNMAA/P4VP and PNCHAA/P4VP blends, because the resonance characteristic of the aromatic ring in PNPAA enhances the inter-association hydrogen bonding with P4VP based on FIFIR and solid-state NMR analyses. |
URI: | http://dx.doi.org/10.1021/jp910849y http://hdl.handle.net/11536/5851 |
ISSN: | 1520-6106 |
DOI: | 10.1021/jp910849y |
期刊: | JOURNAL OF PHYSICAL CHEMISTRY B |
Volume: | 114 |
Issue: | 4 |
起始頁: | 1603 |
結束頁: | 1613 |
顯示於類別: | 期刊論文 |