標題: Resonance Effect on Self- and Inter-Association Hydrogen Bonding Interaction of Polymer Blend
作者: Lin, Chien-Ting
Kuo, Shiao-Wei
Lo, Jen-Chih
Chang, Feng-Chih
應用化學系
Department of Applied Chemistry
公開日期: 4-二月-2010
摘要: A comparative Study of three poly(methacrylamides) containing different N-substitutions was carried Out in order to obtain a better understanding of the resonance effects on the inter-association and self-association hydrogen bonding interactions in polymer blends. DSC and solid-state NMR analyses are employed to Study the relative miscibility of these three binary blends, indicating that the PNPAA/P4VP blend has a better miscibility than the PNMAA/P4VP and PNCHAA/P4VP blends, because the resonance characteristic of the aromatic ring in PNPAA enhances the inter-association hydrogen bonding with P4VP based on FIFIR and solid-state NMR analyses.
URI: http://dx.doi.org/10.1021/jp910849y
http://hdl.handle.net/11536/5851
ISSN: 1520-6106
DOI: 10.1021/jp910849y
期刊: JOURNAL OF PHYSICAL CHEMISTRY B
Volume: 114
Issue: 4
起始頁: 1603
結束頁: 1613
顯示於類別:期刊論文


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