標題: | An Unprecedentedly Huge Square-Grid Copper(II)-Organic Framework Material Built from a Bulky Pyrene-Derived Elongated Cross-Shaped Scaffold |
作者: | Tsai, Chen-Chuan Luo, Tzuoo-Tsair Yin, Jen-Fu Lin, Hong-Cheu Lu, Kuang-Lieh 材料科學與工程學系 Department of Materials Science and Engineering |
公開日期: | 21-九月-2009 |
摘要: | A new bulky pyrene-derived elongated cross-shaped organic scaffold was successfully incorporated into a highly porous, non-interpenetrated square-grid copper(II)-organic framework material with the unprecedentedly huge dimensions of 25.5 x 25.5 angstrom(2), while the layer-to-layer NH center dot center dot center dot N interaction leads to a unique hydrogen-bonded 6(4).8(2)-nbo net. |
URI: | http://dx.doi.org/10.1021/ic900786b http://hdl.handle.net/11536/6664 |
ISSN: | 0020-1669 |
DOI: | 10.1021/ic900786b |
期刊: | INORGANIC CHEMISTRY |
Volume: | 48 |
Issue: | 18 |
起始頁: | 8650 |
結束頁: | 8652 |
顯示於類別: | 期刊論文 |