完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.author | Liao, Hung-Chou | en_US |
dc.contributor.author | Chen, San-Yuan | en_US |
dc.contributor.author | Liu, Dean-Mo | en_US |
dc.date.accessioned | 2014-12-08T15:08:44Z | - |
dc.date.available | 2014-12-08T15:08:44Z | - |
dc.date.issued | 2009-09-08 | en_US |
dc.identifier.issn | 0024-9297 | en_US |
dc.identifier.uri | http://dx.doi.org/10.1021/ma900924y | en_US |
dc.identifier.uri | http://hdl.handle.net/11536/6685 | - |
dc.description.abstract | A novel method was used to synthesize CdS single-crystal nanorods directly in the presence of conjugated polymer poly(3-hexylthiophene-2,5-diyl) (P3FIT), where the P3HT is acting as a molecular template for geometrical manipulation of CdS nanocrystals and, in the meantime, as in efficient charge conductor in composite form. Such a templating process allows the CdS nanorods with various aspect ratios to be easily manufactured via a controlled solvency of a cosolvent Mixture, under which the conformational variation of the P3HT chain can be manipulated. The mechanism of in situ growth of high-aspect-ratio CdS nanorod is proposed based on spectroscopic analysis. A considerably improved PL quenching was detected for the nanorods and suggested a result of electronic coupling between the high-aspect-ratio CdS nanorods and the conducting polymer matrix. A photovoltaic device consisting of CdS nanorods with aspect ratio of ea. 16 and the conjugated polymer poly(3-hexylthiophene) was well assembled and showed a power conversion efficiency of as high as 2.9% under air mass (AM) 1.5 global solar conditions. | en_US |
dc.language.iso | en_US | en_US |
dc.title | In-Situ Growing CdS Single-Crystal Nanorods via P3HT Polymer as a Soft Template, for Enhancing Photovoltaic Performance | en_US |
dc.type | Article | en_US |
dc.identifier.doi | 10.1021/ma900924y | en_US |
dc.identifier.journal | MACROMOLECULES | en_US |
dc.citation.volume | 42 | en_US |
dc.citation.issue | 17 | en_US |
dc.citation.spage | 6558 | en_US |
dc.citation.epage | 6563 | en_US |
dc.contributor.department | 材料科學與工程學系 | zh_TW |
dc.contributor.department | Department of Materials Science and Engineering | en_US |
dc.identifier.wosnumber | WOS:000269635900029 | - |
dc.citation.woscount | 53 | - |
顯示於類別: | 期刊論文 |