The polarisability potential as a steric index

標題:	The polarisability potential as a steric index
作者:	Camacho, Cristopher Mata-Segreda, Julio F. 應用化學系應用化學系分子科學碩博班 Department of Applied Chemistry Institute of Molecular science
關鍵字:	acid-catalysed ester hydrolysis;moment of inertia;polarisability potential;steric effect;Taft parameter;torsional barrier
公開日期:	1-十月-2010
摘要:	The acid-catalysed hydrolysis of carboxylic esters is the reference chemical reaction used for the empirical evaluation of steric effects. In this work, the polarisability potential (Hehre, et al., J. Am. Chem. Soc. 1986, 108, 1711-1712) is identified as quantum-mechanical size of substituent groups. Correlation is found between this quantity and reactivity features of the reference reaction. Copyright (C) 2010 John Wiley & Sons, Ltd.
URI:	http://dx.doi.org/10.1002/poc.1742 http://hdl.handle.net/11536/7012
ISSN:	0894-3230
DOI:	10.1002/poc.1742
期刊:	JOURNAL OF PHYSICAL ORGANIC CHEMISTRY
Volume:	23
Issue:	10
起始頁:	955
結束頁:	959
顯示於類別：	會議論文

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