The polarisability potential as a steric index

doi:10.1002/poc.1742

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DC Field	Value	Language
dc.contributor.author	Camacho, Cristopher	en_US
dc.contributor.author	Mata-Segreda, Julio F.	en_US
dc.date.accessioned	2014-12-08T15:09:12Z	-
dc.date.available	2014-12-08T15:09:12Z	-
dc.date.issued	2010-10-01	en_US
dc.identifier.issn	0894-3230	en_US
dc.identifier.uri	http://dx.doi.org/10.1002/poc.1742	en_US
dc.identifier.uri	http://hdl.handle.net/11536/7012	-
dc.description.abstract	The acid-catalysed hydrolysis of carboxylic esters is the reference chemical reaction used for the empirical evaluation of steric effects. In this work, the polarisability potential (Hehre, et al., J. Am. Chem. Soc. 1986, 108, 1711-1712) is identified as quantum-mechanical size of substituent groups. Correlation is found between this quantity and reactivity features of the reference reaction. Copyright (C) 2010 John Wiley & Sons, Ltd.	en_US
dc.language.iso	en_US	en_US
dc.subject	acid-catalysed ester hydrolysis	en_US
dc.subject	moment of inertia	en_US
dc.subject	polarisability potential	en_US
dc.subject	steric effect	en_US
dc.subject	Taft parameter	en_US
dc.subject	torsional barrier	en_US
dc.title	The polarisability potential as a steric index	en_US
dc.type	Article; Proceedings Paper	en_US
dc.identifier.doi	10.1002/poc.1742	en_US
dc.identifier.journal	JOURNAL OF PHYSICAL ORGANIC CHEMISTRY	en_US
dc.citation.volume	23	en_US
dc.citation.issue	10	en_US
dc.citation.spage	955	en_US
dc.citation.epage	959	en_US
dc.contributor.department	應用化學系	zh_TW
dc.contributor.department	應用化學系分子科學碩博班	zh_TW
dc.contributor.department	Department of Applied Chemistry	en_US
dc.contributor.department	Institute of Molecular science	en_US
dc.identifier.wosnumber	WOS:000283338800012	-
Appears in Collections:	Conferences Paper

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