完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.author | Camacho, Cristopher | en_US |
dc.contributor.author | Mata-Segreda, Julio F. | en_US |
dc.date.accessioned | 2014-12-08T15:09:12Z | - |
dc.date.available | 2014-12-08T15:09:12Z | - |
dc.date.issued | 2010-10-01 | en_US |
dc.identifier.issn | 0894-3230 | en_US |
dc.identifier.uri | http://dx.doi.org/10.1002/poc.1742 | en_US |
dc.identifier.uri | http://hdl.handle.net/11536/7012 | - |
dc.description.abstract | The acid-catalysed hydrolysis of carboxylic esters is the reference chemical reaction used for the empirical evaluation of steric effects. In this work, the polarisability potential (Hehre, et al., J. Am. Chem. Soc. 1986, 108, 1711-1712) is identified as quantum-mechanical size of substituent groups. Correlation is found between this quantity and reactivity features of the reference reaction. Copyright (C) 2010 John Wiley & Sons, Ltd. | en_US |
dc.language.iso | en_US | en_US |
dc.subject | acid-catalysed ester hydrolysis | en_US |
dc.subject | moment of inertia | en_US |
dc.subject | polarisability potential | en_US |
dc.subject | steric effect | en_US |
dc.subject | Taft parameter | en_US |
dc.subject | torsional barrier | en_US |
dc.title | The polarisability potential as a steric index | en_US |
dc.type | Article; Proceedings Paper | en_US |
dc.identifier.doi | 10.1002/poc.1742 | en_US |
dc.identifier.journal | JOURNAL OF PHYSICAL ORGANIC CHEMISTRY | en_US |
dc.citation.volume | 23 | en_US |
dc.citation.issue | 10 | en_US |
dc.citation.spage | 955 | en_US |
dc.citation.epage | 959 | en_US |
dc.contributor.department | 應用化學系 | zh_TW |
dc.contributor.department | 應用化學系分子科學碩博班 | zh_TW |
dc.contributor.department | Department of Applied Chemistry | en_US |
dc.contributor.department | Institute of Molecular science | en_US |
dc.identifier.wosnumber | WOS:000283338800012 | - |
顯示於類別: | 會議論文 |