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dc.contributor.author林奕佑en_US
dc.contributor.authorLin, Yi-Yoen_US
dc.contributor.author裘性天en_US
dc.contributor.author李紫原en_US
dc.contributor.authorChiu, Hsin-Tienen_US
dc.contributor.authorLee, Chi-Youngen_US
dc.date.accessioned2014-12-12T02:35:03Z-
dc.date.available2014-12-12T02:35:03Z-
dc.date.issued2012en_US
dc.identifier.urihttp://140.113.39.130/cdrfb3/record/nctu/#GT070052407en_US
dc.identifier.urihttp://hdl.handle.net/11536/72503-
dc.description.abstract於本論文中,我們利用化學氣相沉積法在高濃度的氫氣環境下,伴隨 鉀金屬催化輔助乙炔在低溫裂解,成功製備出奈米碳纖維。並且在反應後, 能夠藉由去離子水沖洗,輕易地去除所使用的鉀金屬,得到無金屬殘留的 奈米碳纖維。經由穿透式電子顯微鏡之繞射,鑑定此方法合成之一維碳材 料為無晶相的奈米碳纖維。根據實驗所觀察之結果,我們提出鉀金屬催化 的氣液固相反應的成長機制。在反應過程中,液相的鉀金屬在高溫下輔助 乙炔裂解成非晶相的碳,然後在鉀金屬之間沉積,並持續的將部分的液態 鉀金屬往上拉升,形成一維的碳纖維。經由此方法所合成的奈米碳纖維, 在場發射的特性上,具備高穩定性、低起始電場(Eto : 2.63 V/μm)、高場發射電流密度( Jmax : 12.5 mA/cm^2 於 5.50 V/μm 電場下)及高場增強因子(β: 1650)。並且經由電化學方法量測,顯示此奈米碳纖維電極,具備高表面積的優勢。此特性使得奈米碳纖維,在場發射裝置及電極的應用上,可望成為具有潛力的材料。zh_TW
dc.description.abstractAmorphous carbon nanofibers (a-CNFs) were grown on Ti foils using K as the catalyst to assist the thermal decomposition of C2H2 in a H2-rich environment at 723 K. After K was removed with water, a-CNFs with lengths up to tens of um and diameters 30 - 80 nm were observed. The growth of a-CNFs depended on the reaction conditions highly. A vapor-liquid-solid (VLS) growth mechanism is proposed to rationalize the growth process. The electrochemical surface area (ESA) of an a-CNFs on Ti sample (geometrical surface area 0.194 cm^2 ) was determined to be 0.386 cm^2. The field emission properties, turn-on field Eto and field enhancement factor b, of an a-CNFs on Ti were determined to be 2.63 V/um and 1650, respectively, while Jmax reached 12.5 mA/cm^2 at 5.50 V/um. The field emission current sustained up to 15 h at the applied voltage.en_US
dc.language.isoen_USen_US
dc.subject化學氣相沉積zh_TW
dc.subject奈米碳纖維zh_TW
dc.subject鉀金屬zh_TW
dc.subjectCVDen_US
dc.subjectCNFsen_US
dc.subjectKen_US
dc.title利用鉀金屬輔助化學氣相沉積低溫裂解乙炔製備奈米碳纖維zh_TW
dc.titleLow Temperature Chemical Vapor Deposition of Amorphous Carbon Nanofibers from Acetylene Using Potassium as the Catalysten_US
dc.typeThesisen_US
dc.contributor.department應用化學系分子科學碩博士班zh_TW
Appears in Collections:Thesis