Photochemistry of acetone in the presence of exocyclic olefins: An unexpected competition between the photo-Conia and Paterno-Buchi reactions

標題:	Photochemistry of acetone in the presence of exocyclic olefins: An unexpected competition between the photo-Conia and Paterno-Buchi reactions
作者:	Chung, WS Ho, CC 交大名義發表應用化學系 National Chiao Tung University Department of Applied Chemistry
公開日期:	7-Feb-1997
摘要:	When irradiated in the presence of several exocyclic olefins, acetone undergoes homoalkylation with the olefins to form a series of 4-cycloalkylbutan-2-ones (with quantum yields of 0.14 +/- 0.01) rather than exhibiting the expected Paterno-Buchi reaction; in contrast, the photolysis of perdeuteriated acetone gave both types of products.
URI:	http://dx.doi.org/10.1039/a607415d http://hdl.handle.net/11536/727
ISSN:	1359-7345
DOI:	10.1039/a607415d
期刊:	CHEMICAL COMMUNICATIONS
Volume:
Issue:	3
起始頁:	317
結束頁:	318
Appears in Collections:	Articles

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