完整后设资料纪录
DC 栏位 | 值 | 语言 |
---|---|---|
dc.contributor.author | 戴宏哲 | en_US |
dc.contributor.author | Tai, Hung-Che | en_US |
dc.contributor.author | 庄士卿 | en_US |
dc.contributor.author | Chuang, Shih-Ching | en_US |
dc.date.accessioned | 2014-12-12T02:38:12Z | - |
dc.date.available | 2014-12-12T02:38:12Z | - |
dc.date.issued | 2013 | en_US |
dc.identifier.uri | http://140.113.39.130/cdrfb3/record/nctu/#GT070052564 | en_US |
dc.identifier.uri | http://hdl.handle.net/11536/73531 | - |
dc.description.abstract | 本篇论文主要是利用不同亲核试剂与烯炔类及多炔类化合物进行共轭加成反应,去探讨其反应路径及加成的位向选择,进而得到高效率的亲核加成方式。本文将会探讨最佳化反应条件,接着更换起始物上的取代基去进行反应,探讨其推拉电子效应以及立体结构对反应性的影响。之后进行光谱分析,另外也利用二维核磁共振光谱、NOE获得该化合物结构。 | zh_TW |
dc.description.abstract | In this thesis, we study reactivity of conjugate addition with different nucleophiles toward enyne and polynes and then get an efficient way of nucleophilic addition. We optimize the reaction conditions, and study reactivity scope variously substitated enynes and polynes.As well as effects of electron-withdrawing functionality and three-dimensional structure on reactivity.The spectroscopic techniques, NMR, IR, MASS, two-dimensional NMR spectroscopy and NOE were used to identify the compound structure. | en_US |
dc.language.iso | zh_TW | en_US |
dc.subject | 麦可共轭加成反应 | zh_TW |
dc.subject | 亲核试剂 | zh_TW |
dc.subject | 炔类化合物 | zh_TW |
dc.subject | Michael Conjugate Additions | en_US |
dc.subject | Nucleophilic | en_US |
dc.subject | Alkynyl Compounds | en_US |
dc.title | 亲核试剂与炔类化合物进行麦可共轭加成反应之探讨 | zh_TW |
dc.title | Study of Nucleophilic Michael Conjugate Additions to Alkynyl Compounds | en_US |
dc.type | Thesis | en_US |
dc.contributor.department | 应用化学系硕博士班 | zh_TW |
显示于类别: | Thesis |