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dc.contributor.authorIwakura, Izumien_US
dc.contributor.authorYabushita, Atsushien_US
dc.contributor.authorKobayashi, Takayoshien_US
dc.date.accessioned2014-12-08T15:10:44Z-
dc.date.available2014-12-08T15:10:44Z-
dc.date.issued2008-11-01en_US
dc.identifier.issn1434-1948en_US
dc.identifier.urihttp://dx.doi.org/10.1002/ejic.200800532en_US
dc.identifier.urihttp://hdl.handle.net/11536/8215-
dc.description.abstractThe excited-state dynamics of Ru(II) (TPP) (CO) (acetone) (TPP = tetraphenylporphyrin) was investigated by using a sub-5-fs pulse, In previous studies, the fluorescence lifetime of Ru(II)-(TPP)(CO) could not be resolved and was reported to be <1 ps. Analysis of the six-coordinate complexes of Ru(II)(TPP)(CO)(acetone) showed that (1)Q(x)(pi,pi*) had a lifetime of 140 +/- 20 fs and the lifetime of (3)(d,pi*) was 560 +/- 150 fs. Stimulated emission due to a spin-forbidden transition from (3)(pi,pi*) to the ground state was observed for the first time. (C) Wiley-VCH Verlag GmbH & Co. KGdA, 69451 Weinheim, Germany, 2008)en_US
dc.language.isoen_USen_US
dc.subjectRutheniumen_US
dc.subjectPhotochemistryen_US
dc.subjectLuminescenceen_US
dc.subjectFemtochemistryen_US
dc.subjectLaser spectroscopyen_US
dc.titleUltrafast Vibronic Processes in a Ru-Porphyrin Complexen_US
dc.typeArticleen_US
dc.identifier.doi10.1002/ejic.200800532en_US
dc.identifier.journalEUROPEAN JOURNAL OF INORGANIC CHEMISTRYen_US
dc.citation.volumeen_US
dc.citation.issue31en_US
dc.citation.spage4856en_US
dc.citation.epage4860en_US
dc.contributor.department電子物理學系zh_TW
dc.contributor.departmentDepartment of Electrophysicsen_US
dc.identifier.wosnumberWOS:000261049700003-
dc.citation.woscount4-
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