Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Lee, Yuan-Pern | en_US |
dc.contributor.author | Wu, Yu-Jong | en_US |
dc.contributor.author | Hougen, Jon T. | en_US |
dc.date.accessioned | 2014-12-08T15:10:55Z | - |
dc.date.available | 2014-12-08T15:10:55Z | - |
dc.date.issued | 2008-09-14 | en_US |
dc.identifier.issn | 0021-9606 | en_US |
dc.identifier.uri | http://dx.doi.org/10.1063/1.2975340 | en_US |
dc.identifier.uri | http://hdl.handle.net/11536/8353 | - |
dc.description.abstract | Observation of two weak absorption lines from the E (K=1) level and one intense feature from A (K=0) for degenerate modes v(4) and v(6) of CH(3)F provides direct spectral evidence that CH(3)F isolated in p-H(2) rotates about only its symmetry axis, and not about the other two axes. An interaction between A and E vibrational levels caused by the partially hindered spinning rotation is proposed. Conversion of nuclear spin between A and E components of CH(3)F is rapid when p-H(2) contains some o-H(2), but becomes slow when the proportion of o-H(2) is much decreased. (c) 2008 American Institute of Physics. | en_US |
dc.language.iso | en_US | en_US |
dc.title | Direct spectral evidence of single-axis rotation and ortho-hydrogen-assisted nuclear spin conversion of CH(3)F in solid para-hydrogen | en_US |
dc.type | Article | en_US |
dc.identifier.doi | 10.1063/1.2975340 | en_US |
dc.identifier.journal | JOURNAL OF CHEMICAL PHYSICS | en_US |
dc.citation.volume | 129 | en_US |
dc.citation.issue | 10 | en_US |
dc.citation.epage | en_US | |
dc.contributor.department | 應用化學系 | zh_TW |
dc.contributor.department | 應用化學系分子科學碩博班 | zh_TW |
dc.contributor.department | Department of Applied Chemistry | en_US |
dc.contributor.department | Institute of Molecular science | en_US |
dc.identifier.wosnumber | WOS:000259883600022 | - |
dc.citation.woscount | 23 | - |
Appears in Collections: | Articles |
Files in This Item:
If it is a zip file, please download the file and unzip it, then open index.html in a browser to view the full text content.