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dc.contributor.authorLee, Yuan-Pernen_US
dc.contributor.authorWu, Yu-Jongen_US
dc.contributor.authorHougen, Jon T.en_US
dc.date.accessioned2014-12-08T15:10:55Z-
dc.date.available2014-12-08T15:10:55Z-
dc.date.issued2008-09-14en_US
dc.identifier.issn0021-9606en_US
dc.identifier.urihttp://dx.doi.org/10.1063/1.2975340en_US
dc.identifier.urihttp://hdl.handle.net/11536/8353-
dc.description.abstractObservation of two weak absorption lines from the E (K=1) level and one intense feature from A (K=0) for degenerate modes v(4) and v(6) of CH(3)F provides direct spectral evidence that CH(3)F isolated in p-H(2) rotates about only its symmetry axis, and not about the other two axes. An interaction between A and E vibrational levels caused by the partially hindered spinning rotation is proposed. Conversion of nuclear spin between A and E components of CH(3)F is rapid when p-H(2) contains some o-H(2), but becomes slow when the proportion of o-H(2) is much decreased. (c) 2008 American Institute of Physics.en_US
dc.language.isoen_USen_US
dc.titleDirect spectral evidence of single-axis rotation and ortho-hydrogen-assisted nuclear spin conversion of CH(3)F in solid para-hydrogenen_US
dc.typeArticleen_US
dc.identifier.doi10.1063/1.2975340en_US
dc.identifier.journalJOURNAL OF CHEMICAL PHYSICSen_US
dc.citation.volume129en_US
dc.citation.issue10en_US
dc.citation.epageen_US
dc.contributor.department應用化學系zh_TW
dc.contributor.department應用化學系分子科學碩博班zh_TW
dc.contributor.departmentDepartment of Applied Chemistryen_US
dc.contributor.departmentInstitute of Molecular scienceen_US
dc.identifier.wosnumberWOS:000259883600022-
dc.citation.woscount23-
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