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dc.contributor.authorChen, S. C.en_US
dc.contributor.authorTu, G. C.en_US
dc.contributor.authorHung, Caryat C. Y.en_US
dc.contributor.authorHuang, C. A.en_US
dc.contributor.authorRei, M. H.en_US
dc.date.accessioned2014-12-08T15:12:16Z-
dc.date.available2014-12-08T15:12:16Z-
dc.date.issued2008-04-30en_US
dc.identifier.issn0376-7388en_US
dc.identifier.urihttp://dx.doi.org/10.1016/j.memsci.2007.12.066en_US
dc.identifier.urihttp://hdl.handle.net/11536/9437-
dc.description.abstractA novel electroplating method of preparing Pd-membrane on an AISI 316L porous stainless steel support is successfully developed by proper control of rotation speed of the support. The use of low-current density with high-rotation speed enables us to avoid hydrogen absorption during electroplating and to prepare smooth thin surfaced membrane with defect free. The electroplated-Pd-membrane shows well property in the hydrogen permeation, flux and excellent permselectivity (H-2/He > 100,000), and is used in a membrane-assisted steam reformer of methanol for the production of high-purity hydrogen. It was also found that the membrane spontaneously exhibited to resist hydrogen embrittlement under the phase-transition temperature of 280 degrees C, when operated in the temperature range of 250-350 degrees C under the hydrogen pressure of 9 kgf/cm(2). (C) 2008 Elsevier B.V. All rights reserved.en_US
dc.language.isoen_USen_US
dc.subjectelectroplatingen_US
dc.subjectporous stainless steelen_US
dc.subjectrotating speeden_US
dc.subjecthydrogen permeationen_US
dc.subjecthydrogen embrittlementen_US
dc.titlePreparation of palladium membrane by electroplating on AISI 316L porous stainless steel supports and its use for methanol steam reformeren_US
dc.typeArticleen_US
dc.identifier.doi10.1016/j.memsci.2007.12.066en_US
dc.identifier.journalJOURNAL OF MEMBRANE SCIENCEen_US
dc.citation.volume314en_US
dc.citation.issue1-2en_US
dc.citation.spage5en_US
dc.citation.epage14en_US
dc.contributor.department材料科學與工程學系zh_TW
dc.contributor.departmentDepartment of Materials Science and Engineeringen_US
dc.identifier.wosnumberWOS:000255994600002-
dc.citation.woscount20-
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