Synthesis of 3,5,7-trioxapentacyclo[7.2.1.0(2,8).0(4,11).0(6,10)]dodecane. A novel diacetal trioxa-cage

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DC Field	Value	Language
dc.contributor.author	Tsai, SH	en_US
dc.contributor.author	Wu, HJ	en_US
dc.contributor.author	Chung, WS	en_US
dc.date.accessioned	2014-12-08T15:02:18Z	-
dc.date.available	2014-12-08T15:02:18Z	-
dc.date.issued	1996-10-01	en_US
dc.identifier.issn	0009-4536	en_US
dc.identifier.uri	http://hdl.handle.net/11536/988	-
dc.description.abstract	3,5,7-Trioxapentacyclo[7.2.1.0(2,8).0(4,11).0(6,10)] dodecane, the parent compound of novel diacetal trioxa-cages, was synthesized from maleic anhydride cyclopentadiene adduct 1 by a four-step sequence. Attempts for the synthesis of monoaza dioxa-cage 12 failed. Ozonolysis of compound 9 in CH2Cl2-EtOH (1:1) at -78 degrees C followed by reduction with Me(2)S gave 13 in 65% yield.	en_US
dc.language.iso	en_US	en_US
dc.subject	unsubstituted diacetal trioxa-cage	en_US
dc.title	Synthesis of 3,5,7-trioxapentacyclo[7.2.1.0(2,8).0(4,11).0(6,10)]dodecane. A novel diacetal trioxa-cage	en_US
dc.type	Article	en_US
dc.identifier.journal	JOURNAL OF THE CHINESE CHEMICAL SOCIETY	en_US
dc.citation.volume	43	en_US
dc.citation.issue	5	en_US
dc.citation.spage	445	en_US
dc.citation.epage	449	en_US
dc.contributor.department	交大名義發表	zh_TW
dc.contributor.department	應用化學系	zh_TW
dc.contributor.department	National Chiao Tung University	en_US
dc.contributor.department	Department of Applied Chemistry	en_US
dc.identifier.wosnumber	WOS:A1996VT72400011	-
dc.citation.woscount	17	-
Appears in Collections:	Articles