標題: Synthesis of 3,5,7-trioxapentacyclo[7.2.1.0(2,8).0(4,11).0(6,10)]dodecane. A novel diacetal trioxa-cage
作者: Tsai, SH
Wu, HJ
Chung, WS
交大名義發表
應用化學系
National Chiao Tung University
Department of Applied Chemistry
關鍵字: unsubstituted diacetal trioxa-cage
公開日期: 1-Oct-1996
摘要: 3,5,7-Trioxapentacyclo[7.2.1.0(2,8).0(4,11).0(6,10)] dodecane, the parent compound of novel diacetal trioxa-cages, was synthesized from maleic anhydride cyclopentadiene adduct 1 by a four-step sequence. Attempts for the synthesis of monoaza dioxa-cage 12 failed. Ozonolysis of compound 9 in CH2Cl2-EtOH (1:1) at -78 degrees C followed by reduction with Me(2)S gave 13 in 65% yield.
URI: http://hdl.handle.net/11536/988
ISSN: 0009-4536
期刊: JOURNAL OF THE CHINESE CHEMICAL SOCIETY
Volume: 43
Issue: 5
起始頁: 445
結束頁: 449
Appears in Collections:Articles