Synthesis and thermal decomposition of Zn(tda)H2O [tda = S(CH2COO)(2)(2-)]
| dc.citation.epage | 9636 | en_US |
| dc.citation.issue | 24 | en_US |
| dc.citation.spage | 9634 | en_US |
| dc.citation.volume | 45 | en_US |
| dc.citation.woscount | 16 | |
| dc.contributor.author | Wu, Ming-Cheng | en_US |
| dc.contributor.author | Lee, Chi-Shen | en_US |
| dc.contributor.department | 應用化學系 | zh_TW |
| dc.contributor.department | 應用化學系分子科學碩博班 | zh_TW |
| dc.contributor.department | Department of Applied Chemistry | en_US |
| dc.contributor.department | Institute of Molecular science | en_US |
| dc.date.accessioned | 2014-12-08T15:15:21Z | |
| dc.date.available | 2014-12-08T15:15:21Z | |
| dc.date.issued | 2006-11-27 | en_US |
| dc.description.abstract | A novel two-dimensional coordination polymer Zn(tda)H2O [tda = S(CH2COO)(2)(2-)] was synthesized under hydrothermal conditions. The compound crystallized in monoclinic space group P2(1) with a = 16.4154(17) angstrom, b = 5.2133(6) angstrom, c = 16.4210(17) angstrom, beta = 114.165(2)degrees, V = 1282.1(2) angstrom(3), and Z = 8. The structure features two-dimensional, noncentrosymmetric networks with a pseudohexagonal network of Zn2+ coordinated by tda and water molecules. Zn(tda)H2O decomposed at T > 300 degrees C to form a ZnO sponge with a surface area similar to 40 m(2)/g, which makes it an attractive precursor for nanoporous ZnO. | en_US |
| dc.identifier.doi | 10.1021/ic061531c | en_US |
| dc.identifier.issn | 0020-1669 | en_US |
| dc.identifier.journal | INORGANIC CHEMISTRY | en_US |
| dc.identifier.uri | http://dx.doi.org/10.1021/ic061531c | en_US |
| dc.identifier.uri | https://ir.lib.nycu.edu.tw/handle/11536/11520 | |
| dc.identifier.wosnumber | WOS:000242124300010 | |
| dc.language.iso | en_US | en_US |
| dc.title | Synthesis and thermal decomposition of Zn(tda)H2O [tda = S(CH2COO)(2)(2-)] | en_US |
| dc.type | Article | en_US |