Effect of Fe2+ on catalytic oxidation in a fluidized bed reactor
| dc.citation.epage | 2006 | en_US |
| dc.citation.issue | 12 | en_US |
| dc.citation.spage | 1997 | en_US |
| dc.citation.volume | 39 | en_US |
| dc.citation.woscount | 30 | |
| dc.contributor.author | Chou, SS | en_US |
| dc.contributor.author | Huang, CP | en_US |
| dc.contributor.author | Huang, YH | en_US |
| dc.contributor.department | 環境工程研究所 | zh_TW |
| dc.contributor.department | Institute of Environmental Engineering | en_US |
| dc.date.accessioned | 2014-12-08T15:46:05Z | |
| dc.date.available | 2014-12-08T15:46:05Z | |
| dc.date.issued | 1999-11-01 | en_US |
| dc.description.abstract | The aim of this study was to investigate the effect of Fe2+ on the catalytic oxidation in the fluidized-bed reactor (FBR) applying supported gamma-FeOOH as the carrier. Processes without Fe2+ addition and with Fe2+ addition (FBR-Fenton method) were performed on the oxidation of benzoic acid (BA) by H2O2. When Fe2+ was not added in the FBR, the high COD removal at low pH was caused by homogeneous catalysis of Fe2+ formed via reductive dissolution of gamma-FeOOH. In the FBR-Fenton process, both mineralization of organics and crystallization of Fe(III) were simultaneously well performed under adequate condition. The reaction mechanism, including the reductive dissolution and crystallization of gamma-FeOOH as well as the oxidation of BA, was proposed based on the experimental results. (C)1999 Elsevier Science Ltd. All rights reserved. | en_US |
| dc.identifier.doi | 10.1016/S0045-6535(99)00089-2 | en_US |
| dc.identifier.issn | 0045-6535 | en_US |
| dc.identifier.journal | CHEMOSPHERE | en_US |
| dc.identifier.uri | http://dx.doi.org/10.1016/S0045-6535(99)00089-2 | en_US |
| dc.identifier.uri | https://ir.lib.nycu.edu.tw/handle/11536/30989 | |
| dc.identifier.wosnumber | WOS:000082900100002 | |
| dc.language.iso | en_US | en_US |
| dc.subject | catalyst | en_US |
| dc.subject | crystallization | en_US |
| dc.subject | fluidized-bed | en_US |
| dc.subject | hydrogen peroxide | en_US |
| dc.subject | iron oxide | en_US |
| dc.subject | oxidation | en_US |
| dc.title | Effect of Fe2+ on catalytic oxidation in a fluidized bed reactor | en_US |
| dc.type | Article | en_US |