Determination of the interaction within polyester-based solid polymer electrolyte using FTIR spectroscopy
| dc.citation.epage | 996 | en_US |
| dc.citation.issue | 4 | en_US |
| dc.citation.spage | 989 | en_US |
| dc.citation.volume | 48 | en_US |
| dc.citation.woscount | 22 | |
| dc.contributor.author | Wu, I-Der | en_US |
| dc.contributor.author | Chang, Feng-Chih | en_US |
| dc.contributor.department | 應用化學系 | zh_TW |
| dc.contributor.department | Department of Applied Chemistry | en_US |
| dc.date.accessioned | 2014-12-08T15:14:42Z | |
| dc.date.available | 2014-12-08T15:14:42Z | |
| dc.date.issued | 2007-02-09 | en_US |
| dc.description.abstract | Characterization and interaction behavior between Li+ ion and C=O groups of a series polyester electrolyte have been thoroughly examined using Fourier transform infrared (FTIR). The "free/Li+ bonded" C=O absorptivity coefficient of the LiClO4/polyester can be determined quantitatively using FTIR spectrum ranging from 1800 to 1650 cm(-1) at 80 degrees C. Results from curve fitting show that the "free/Li+ bonded" C=O absorptivity coefficient is 0.144 +/- 0.005. The C=O group of polymer electrolyte shows strong interaction with Li+ ion and a limit value of 95% "Li-divided by bonded" C = O is approached in the polymer electrolyte system when the Li+ ion equivalent fraction is about 0.28. The molecular structure of polyester electrolyte does not affect significantly the efficiency of interaction between Li+ ion and C=O. (c) 2007 Published by Elsevier Ltd. | en_US |
| dc.identifier.doi | 10.1016/j.polymer.2006.12.045 | en_US |
| dc.identifier.issn | 0032-3861 | en_US |
| dc.identifier.journal | POLYMER | en_US |
| dc.identifier.uri | http://dx.doi.org/10.1016/j.polymer.2006.12.045 | en_US |
| dc.identifier.uri | https://ir.lib.nycu.edu.tw/handle/11536/11137 | |
| dc.identifier.wosnumber | WOS:000244509400008 | |
| dc.language.iso | en_US | en_US |
| dc.subject | polymer electrolyte | en_US |
| dc.subject | polyester | en_US |
| dc.subject | FTIR | en_US |
| dc.title | Determination of the interaction within polyester-based solid polymer electrolyte using FTIR spectroscopy | en_US |
| dc.type | Article | en_US |