Correlation between N 1s XPS binding energy and bond distance in metal amido, imido, and nitrido complexes
| dc.citation.epage | 4518 | en_US |
| dc.citation.issue | 15 | en_US |
| dc.citation.spage | 4516 | en_US |
| dc.citation.volume | 42 | en_US |
| dc.citation.woscount | 27 | |
| dc.contributor.author | Wu, JB | en_US |
| dc.contributor.author | Lin, YF | en_US |
| dc.contributor.author | Wang, JL | en_US |
| dc.contributor.author | Chang, PJ | en_US |
| dc.contributor.author | Tasi, CP | en_US |
| dc.contributor.author | Lu, CC | en_US |
| dc.contributor.author | Chiu, HT | en_US |
| dc.contributor.author | Yang, YW | en_US |
| dc.contributor.department | 應用化學系 | zh_TW |
| dc.contributor.department | Department of Applied Chemistry | en_US |
| dc.date.accessioned | 2014-12-08T15:40:37Z | |
| dc.date.available | 2014-12-08T15:40:37Z | |
| dc.date.issued | 2003-07-28 | en_US |
| dc.description.abstract | Synchrotron-based X-ray photoelectron spectroscopy is used to measure N 1s binding energies of several metal amido, imido, and nitrido complexes of group 5 and 6 metals. The N 1s binding energy decreases as the formal M-N bond order increases. A simple correlation between the contraction of the M-N bond and the lowering of binding energy is also observed. This correlation supports a notion that the bonding character of a linear metal-imido linkage resembles that of a metal-nitrido linkage closely. | en_US |
| dc.identifier.issn | 0020-1669 | en_US |
| dc.identifier.journal | INORGANIC CHEMISTRY | en_US |
| dc.identifier.uri | https://ir.lib.nycu.edu.tw/handle/11536/27701 | |
| dc.identifier.wosnumber | WOS:000184264400011 | |
| dc.language.iso | en_US | en_US |
| dc.title | Correlation between N 1s XPS binding energy and bond distance in metal amido, imido, and nitrido complexes | en_US |
| dc.type | Article | en_US |