Electron-Transfer-Induced Intramolecular Heck Carbonylation Reactions Leading to Benzolactones and Benzolactams
| dc.citation.epage | 3021 | en_US |
| dc.citation.spage | 3015 | en_US |
| dc.citation.volume | 50 | en_US |
| dc.contributor.author | Fukuyama, Takahide | en_US |
| dc.contributor.author | Bando, Takanobu | en_US |
| dc.contributor.author | Ryu, Ilhyong | en_US |
| dc.contributor.department | 應用化學系 | zh_TW |
| dc.contributor.department | Department of Applied Chemistry | en_US |
| dc.date.accessioned | 2018-08-21T05:53:52Z | |
| dc.date.available | 2018-08-21T05:53:52Z | |
| dc.date.issued | 2018-08-01 | en_US |
| dc.description.abstract | A metal-catalyst-free intramolecular Heck carbonylation reaction of benzyl alcohols and benzyl amines with carbon monoxide under heating at 250 degrees C affords the corresponding benzolactones and benzolactams in good to excellent yields. A hybrid radical/ionic chain mechanism, involving electron transfer from radical anions generated by nucleophilic attack of alcohols or amines on intermediate acyl radicals, is proposed. | en_US |
| dc.identifier.doi | 10.1055/s-0037-1609964 | en_US |
| dc.identifier.issn | 0039-7881 | en_US |
| dc.identifier.journal | SYNTHESIS-STUTTGART | en_US |
| dc.identifier.uri | http://dx.doi.org/10.1055/s-0037-1609964 | en_US |
| dc.identifier.uri | https://ir.lib.nycu.edu.tw/handle/11536/145276 | |
| dc.identifier.wosnumber | WOS:000439116100022 | en_US |
| dc.language.iso | en_US | en_US |
| dc.subject | carbonylation | en_US |
| dc.subject | electron transfer | en_US |
| dc.subject | radical reactions | en_US |
| dc.subject | metal-free | en_US |
| dc.subject | lactones | en_US |
| dc.subject | lactams | en_US |
| dc.title | Electron-Transfer-Induced Intramolecular Heck Carbonylation Reactions Leading to Benzolactones and Benzolactams | en_US |
| dc.type | Article | en_US |
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