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Intercepting the Nazarov Oxyallyl Intermediate with -Formylvinyl Anion Equivalents to Access Formal Morita-Baylis-Hillman Alkylation Products

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dc.citation.epage1490en_US
dc.citation.spage1486en_US
dc.citation.volume28en_US
dc.contributor.authorWu, Yen-Kuen_US
dc.contributor.authorLin, Rongrongen_US
dc.contributor.authorWest, F. G.en_US
dc.contributor.department應用化學系zh_TW
dc.contributor.departmentDepartment of Applied Chemistryen_US
dc.date.accessioned2018-08-21T05:54:18Z
dc.date.available2018-08-21T05:54:18Z
dc.date.issued2017-07-01en_US
dc.description.abstractA Lewis acid catalyzed cationic domino reaction involving sequential electrocyclization and polar addition of allenol ethers onto the resulting oxyallyl species is described. The overall sequence allows a highly stereoselective synthesis of densely substituted cyclopentanoid compounds containing -formylvinyl functionality which is formally equivalent to products of a Morita-Baylis-Hillman alkylation process.en_US
dc.identifier.doi10.1055/s-0036-1588769en_US
dc.identifier.issn0936-5214en_US
dc.identifier.journalSYNLETTen_US
dc.identifier.urihttp://dx.doi.org/10.1055/s-0036-1588769en_US
dc.identifier.urihttps://ir.lib.nycu.edu.tw/handle/11536/145789
dc.identifier.wosnumberWOS:000405534400019en_US
dc.language.isoen_USen_US
dc.subjectinterrupted Nazarov cyclizationen_US
dc.subjectoxyallyl cationen_US
dc.subjectallenol ethersen_US
dc.subjectcarbonyl umpolungen_US
dc.subjectMorita-Baylis-Hillman alkylationen_US
dc.titleIntercepting the Nazarov Oxyallyl Intermediate with -Formylvinyl Anion Equivalents to Access Formal Morita-Baylis-Hillman Alkylation Productsen_US
dc.typeArticleen_US

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