Pd/light-induced alkyl-alkenyl coupling reaction between unactivated alkyl iodides and alkenylboronic acids
| dc.citation.epage | 1270 | en_US |
| dc.citation.issue | 10 | en_US |
| dc.citation.spage | 1266 | en_US |
| dc.citation.volume | 7 | en_US |
| dc.citation.woscount | 0 | en_US |
| dc.contributor.author | Huang, Hsin-Ju | en_US |
| dc.contributor.author | Wang, Yi-Ting | en_US |
| dc.contributor.author | Wu, Yen-Ku | en_US |
| dc.contributor.author | Ryu, Ilhyong | en_US |
| dc.contributor.department | 應用化學系 | zh_TW |
| dc.contributor.department | Department of Applied Chemistry | en_US |
| dc.date.accessioned | 2020-07-01T05:22:11Z | |
| dc.date.available | 2020-07-01T05:22:11Z | |
| dc.date.issued | 2020-05-21 | en_US |
| dc.description.abstract | Alkyl-alkenyl coupling reaction between unactivated alkyl iodides and 2-arylalkenylboronic acids utilizing a Pd/light combined system was studied. This reaction provided 2-alkylarylalkenes in good yields. It is proposed that in this reaction alkyl radicals are formed by SET from a Pd catalyst to alkyl iodides, which then undergo addition reactions to form C-C double bonds of alkenyl boronic acids and the subsequent beta-fragmentation of boronyl radicals leads to the formation of alkyl-substituted arylalkenes. | en_US |
| dc.identifier.doi | 10.1039/d0qo00318b | en_US |
| dc.identifier.issn | 2052-4129 | en_US |
| dc.identifier.journal | ORGANIC CHEMISTRY FRONTIERS | en_US |
| dc.identifier.uri | http://dx.doi.org/10.1039/d0qo00318b | en_US |
| dc.identifier.uri | https://ir.lib.nycu.edu.tw/handle/11536/154605 | |
| dc.identifier.wosnumber | WOS:000536816700009 | en_US |
| dc.language.iso | en_US | en_US |
| dc.title | Pd/light-induced alkyl-alkenyl coupling reaction between unactivated alkyl iodides and alkenylboronic acids | en_US |
| dc.type | Article | en_US |
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