Dissociation of energy-selected c-C3H6S+ studied with threshold photoelectron-photolon coincidence experiments and calculations
| dc.citation.epage | 480 | en_US |
| dc.citation.issue | 4-6 | en_US |
| dc.citation.spage | 475 | en_US |
| dc.citation.volume | 422 | en_US |
| dc.citation.woscount | 0 | |
| dc.contributor.author | Chiang, SY | en_US |
| dc.contributor.author | Fang, YS | en_US |
| dc.contributor.author | Lin, CN | en_US |
| dc.contributor.department | 應用化學系 | zh_TW |
| dc.contributor.department | Department of Applied Chemistry | en_US |
| dc.date.accessioned | 2014-12-08T15:16:36Z | |
| dc.date.available | 2014-12-08T15:16:36Z | |
| dc.date.issued | 2006-05-10 | en_US |
| dc.description.abstract | The dissociation of energy-selected c-C3H6S+ was investigated in a region 10.2-10.9 eV with a threshold photoelectron-photoion coincidence technique. Branching ratios and average releases of kinetic energy for channel c-C3H6S+ -> H2CS+ + C2H4 were derived from coincidence mass spectra. The measured small releases of kinetic energy near the appearance onset agree with statistical calculations; a linearly extrapolated threshold at 10.39 +/- 0.01 eV agrees with a predicted energy 10.35 eV with the GAUSSIAN-3 method. We discuss plausible mechanisms for c-C3H6S+ dissociating to CH3CS+ + CH3 based on G3B3 calculations to rationalize the absence of CH3CS+ signal in these experiments. (c) 2006 Elsevier B.V. All rights reserved. | en_US |
| dc.identifier.doi | 10.1016/j.cplett.2006.03.020 | en_US |
| dc.identifier.issn | 0009-2614 | en_US |
| dc.identifier.journal | CHEMICAL PHYSICS LETTERS | en_US |
| dc.identifier.uri | http://dx.doi.org/10.1016/j.cplett.2006.03.020 | en_US |
| dc.identifier.uri | https://ir.lib.nycu.edu.tw/handle/11536/12259 | |
| dc.identifier.wosnumber | WOS:000237840200036 | |
| dc.language.iso | en_US | en_US |
| dc.title | Dissociation of energy-selected c-C3H6S+ studied with threshold photoelectron-photolon coincidence experiments and calculations | en_US |
| dc.type | Article | en_US |