Nucleophilic Conjugate 1,5-Addition of Gilman Reagents to (E)-Hex-2-en-4-ynedioates: An Access to ()-Substituted Muconates
| dc.citation.epage | 2232 | en_US |
| dc.citation.issue | 15 | en_US |
| dc.citation.spage | 2223 | en_US |
| dc.citation.volume | 47 | en_US |
| dc.citation.woscount | 1 | en_US |
| dc.contributor.author | Tai, Hung-Che | en_US |
| dc.contributor.author | Chavan, Arjun S. | en_US |
| dc.contributor.author | Chuang, Shih-Ching | en_US |
| dc.contributor.department | 應用化學系 | zh_TW |
| dc.contributor.department | Department of Applied Chemistry | en_US |
| dc.date.accessioned | 2019-04-03T06:38:57Z | |
| dc.date.available | 2019-04-03T06:38:57Z | |
| dc.date.issued | 2015-08-01 | en_US |
| dc.description.abstract | An unusual nucleophilic conjugate addition of organocuprates to enynedioates resulted in chemo- and regioselective formation of ()-addition products, rather than ()-addition products, in moderate to good yields. This addition pattern is different from that with organophosphanes or alkyl amines, and presents a short and efficient method for the preparation of various ()-alkyl- or -aryl-substituted muconates compared with other synthetic approaches. | en_US |
| dc.identifier.doi | 10.1055/s-0034-1378856 | en_US |
| dc.identifier.issn | 0039-7881 | en_US |
| dc.identifier.journal | SYNTHESIS-STUTTGART | en_US |
| dc.identifier.uri | http://dx.doi.org/10.1055/s-0034-1378856 | en_US |
| dc.identifier.uri | https://ir.lib.nycu.edu.tw/handle/11536/128018 | |
| dc.identifier.wosnumber | WOS:000358308300007 | en_US |
| dc.language.iso | en_US | en_US |
| dc.subject | addition reactions | en_US |
| dc.subject | alkynes | en_US |
| dc.subject | cuprates | en_US |
| dc.subject | multicomponent reactions | en_US |
| dc.subject | regioselectivity | en_US |
| dc.title | Nucleophilic Conjugate 1,5-Addition of Gilman Reagents to (E)-Hex-2-en-4-ynedioates: An Access to ()-Substituted Muconates | en_US |
| dc.type | Article | en_US |